Advances in electrochemical science and engineering by Richard C. Alkire, Charles W. Tobias PDF

By Richard C. Alkire, Charles W. Tobias

ISBN-10: 352729385X

ISBN-13: 9783527293858

This sequence, previously edited through Heinz Gerischer and Charls V. Tobias, now edited through Richard C. Alkire and Dieter M. Kolb, has been warmly welcomed by way of scientists world-wide that's mirrored within the reports of the former volumes: 'This is an important e-book for researchers in electrochemistry; it covers parts of either primary and useful significance, with stories of top of the range. the fabric is especially good provided and the alternative of subject matters displays a balanced editorial coverage that's welcomed.' The Analyst

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116,117]), may be indispensable. , [118]). g.. correlation of the emission maxima with the oxidation potentials of the donor or with the reduction potentials of the acceptors [ 1191). , [ 1201). 1 Aromatic Hydrocarbons Aromatic hydrocarbons, with the reaction scheme as described above, play the same key role in ECL studies as in organic electrochemistry and organic UV-VIS spectroscopy. 5,6,11,12-Tetraphenyltetracene(rubrene) and 9,lO-diphenylanthracene (DPA) are the most notable examples (Fig.

Since the electronic coupling elements decrease exponentially with distance, VCT may be expressed as follows: + with p equal to 10-12nm-'. 02eV. 02eV. Only the dependence on the separation distance was considered in the estimation of VCT (according to Eq. (70)), neglecting any effects of molecular orientation. It seems reasonable in the view of Cave and co-workers, and Helms et al. [156,157]. Values of A, and X i can also be predicted from experimental data concerning the electron exchange reactions between a neutral species (A and D) and its own radical anion or cation (A- and D+, respectively).

Adapted from [153]. been obtained. A nearly linear correlation between the ratio of the rate constants k c ~ / k 3and the reciprocal of the longitudinal relaxation time T L of the given solvent was found [153] (according to Eq. (67), k c ~ / k 3= 3&/(l - 4&)), as shown in Fig. 18. 431 for sulfolane, is only marginal. Moreover, the V and X i terms are also expected to be independent of solvent. 02 eV), and that the reaction rate kcT may be M 0). It may also be concluded that the expressed by Eq.

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Advances in electrochemical science and engineering by Richard C. Alkire, Charles W. Tobias


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